| Achievement | How to unlock
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| - Complete a combo of 50 moves (any play mode, any character).
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| - Save the damsel, but is she in distress?.
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| - Stop all assaults in Arkham City.
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| - Complete all augmented reality training exercises.
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| - Reunite the separated couple.
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| - Rescue the fifth hostage from Riddler.
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| - Obtain 24 medals on the original Arkham City ranked maps (as Batman).
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| - Obtain 36 medals on the original Arkham City campaigns (as Batman).
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| - Obtain all 108 medals on the original Arkham City campaigns (as Batman).
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| - Obtain 72 medals on the original Arkham City campaigns (as Batman).
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| - Find someone to play remote Batarang catch with.
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| - There is only one way in.
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| - Stop the contract operative.
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| - Rescue the first hostage from Riddler.
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| - Stop the phone booth killer.
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| - Answer the call for help.
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| - All the world is a stage.
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- Flawless Freeflow Fighter 2.0
| - Complete one combat challenge without taking damage (any character).
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| - Collect enough evidence to locate the gun for hire.
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| - Collect all of Batman's gadgets and upgrades.
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| - Use 5 different Quickfire gadgets in one fight (any play mode).
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| - Rescue all the hostages from Riddler.
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| - Obtain all 72 medals on the original Arkham City ranked maps (as Batman).
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| - Jump off the tallest building in Arkham City and glide for 1 minute without touching the ground.
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| - A deadly game of hide and seek.
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| - Rescue the fourth hostage from Riddler.
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| - Uncover the secret of Arkham City.
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| - Rescue the second hostage from Riddler.
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| - Reveal the mystery watcher.
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| - Perform a perfect combo including all of Batman's combat moves (any play mode).
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| - Main Story, Side Missions, Upgrades, Collectables, New Game Plus and Riddlers Revenge (as Batman).
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| - Rescue the third hostage from Riddler.
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| - Save the medical volunteers.
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| - Track down the serial killer.
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| - Obtain 48 medals on the original Arkham City ranked maps (as Batman).
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| - Have 12 murderous dates with Calendar Man.
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