| Achievement | How to unlock
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| - Complete a combo of 50 moves (any play mode, any character)
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- A Few New Tricks (20 points)
| - Use 5 different Quickfire gadgets in one fight as Robin in Harley Quinn's Revenge.
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| - Save the damsel, but is she in distress?
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- Aggravated Assault (10 points)
| - Stop all assaults in Arkham City.
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| - Complete all augmented reality training exercises.
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- Arkham City Sirens (25 points)
| - Drop in on an old friend.
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- Bargaining Chip (15 points)
| - Reunite the separated couple.
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- Battering Ram (10 points)
| - Shield Bash 5 different thugs.
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| - Defuse all bombs in 3 minutes or less.
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| - Rescue the fifth hostage from Riddler.
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- Breaking and Entering (20 points)
| - Find a way into the secret base.
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- Bronze Revenge (10 points)
| - Obtain 24 medals on the original Arkham City ranked maps (as Batman)
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- Campaign Bronze (10 points)
| - Obtain 36 medals on the original Arkham City campaigns (as Batman)
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- Campaign Gold (40 points)
| - Obtain all 108 medals on the original Arkham City campaigns (as Batman)
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- Campaign Kitty (25 points)
| - Obtain all 108 medals on the original Arkham City campaigns (as Catwoman)
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- Campaign Nightwing (25 points)
| - Obtain 114 medals on the original Arkham City and Nightwing Bundle Pack campaigns (as Nightwing)
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- Campaign Silver (20 points)
| - Obtain 72 medals on the original Arkham City campaigns (as Batman)
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- Campaign Wonder (25 points)
| - Obtain 114 medals on the original Arkham City and Robin Bundle Pack campaigns (as Robin)
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| - Find someone to play remote Batarang catch with.
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- Chimney Sweep (10 points)
| - There is only one way in.
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- Communication Breakdown (10 points)
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- Contract Terminated (25 points)
| - Stop the contract operative.
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| - Rescue the first hostage from Riddler.
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- Dial Z For Murder (25 points)
| - Stop the phone booth killer.
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- Distress Flare (5 points)
| - Answer the call for help.
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- Exit Stage Right (50 points)
| - All the world is a stage.
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- Family Jewels (40 points)
| - Retrieve your stolen goods.
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- Feline Revenge (25 points)
| - Obtain all 72 medals on the original Arkham City ranked maps (as Catwoman)
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- Flawless Freeflow Fighter 2.0 (5 points)
| - Complete one combat challenge without taking damage (any character)
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- Forensic Expert (10 points)
| - Collect enough evidence to locate the gun for hire.
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- Frequent Flyer (10 points)
| - Zip Kick 5 different thugs.
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| - Collect all of Batman's gadgets and upgrades.
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| - Use 5 different Quickfire gadgets in one fight (any play mode)
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| - Rescue all the hostages from Riddler.
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| - Obtain all 72 medals on the original Arkham City ranked maps (as Batman)
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- Gotham Base Jumper (5 points)
| - Jump off the tallest building in Arkham City and glide for 1 minute without touching the ground.
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- Hide And Seek (25 points)
| - A deadly game of hide and seek.
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- How's It Hanging? (20 points)
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| - Rescue the fourth hostage from Riddler.
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- Lost And Found (10 points)
| - Uncover the secret of Arkham City.
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- Lost Property (20 points)
| - No crimefighter should be without this.
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| - Rescue the second hostage from Riddler.
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- Mystery Stalker (15 points)
| - Reveal the mystery watcher.
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- Nightwing Revenge (25 points)
| - Obtain 78 medals on the original Arkham City and Nightwing Bundle Pack ranked maps (as Nightwing)
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- One-Armed Bandit (10 points)
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| - Destroy all Harley Balloons.
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- Pay Your Respects (5 points)
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- Perfect Freeflow 2.0 (5 points)
| - Perform a perfect combo including all of Batman's combat moves (any play mode)
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- Perfect Knight - Day 2 (75 points)
| - Main Story, Side Missions, Upgrades, Collectables, New Game Plus and Riddler's Revenge (as Batman)
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| - Steal the score of a lifetime.
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| - Rescue the third hostage from Riddler.
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- Robin Revenge (25 points)
| - Obtain 78 medals on the original Arkham City and Robin Bundle Pack ranked maps (as Robin)
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| - Save the medical volunteers.
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- Serial Killer (25 points)
| - Track down the serial killer.
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- Silver Revenge (20 points)
| - Obtain 48 medals on the original Arkham City ranked maps (as Batman)
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| - Snap Flash an unarmed thug, an armed thug, an environmental object and a Titan.
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- Sphinx' Riddle (10 points)
| - Complete all 40 of the Catwoman Riddler grid items.
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- Stop the Clock (15 points)
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| - Have 12 murderous dates with Calendar Man.
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- The Last Laugh (40 points)
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- Twice Nightly (75 points)
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- Wrecking Ball (25 points)
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