| Achievement | How to unlock
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| - You obtained an adamantium grade.
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| - You won a fight without changing characters in Campaign.
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| - You won a battle with Captain America and Iron Man.
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- Bad Intentions (5 points)
| - You won a battle with Super Skrull and Doctor Doom.
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| - You used your Breaker to break a Combo.
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| - You won a battle with Thor and Loki.
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| - You finished the Campaign mode.
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| - You chained two Super Attacks.
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| - You finished all character's challenge.
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| - You countered a Super Attack with another Super Attack.
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| - You dodged a Super Attack.
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| - You finished the first part of the Campaign.
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| - You performed a Counter Kick.
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| - You got 100 000 Experience points.
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| - You changed the costume of one of your character.
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| - You won a match without dodging in Campaign.
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| - You won a battle with Human Torch and Iceman.
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| - You won a battle with Phoenix and Human Torch.
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| - You won your first battle in Campaign.
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- Impressive feet (5 points)
| - You performed a Close-Combat.
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- King of the Hill (20 points)
| - You won the arcade mode once.
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- Leading Ladies (5 points)
| - You won a battle with Scarlet Witch and Storm.
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| - You unlocked the highest Rank.
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- Maximum Combo (20 points)
| - You chained 4 Super Attacks by switching characters twice.
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- Need a Doctor? (5 points)
| - You won a battle with Doctor Doom and Doctor Strange.
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| - You won a battle with Spider-Man and Venom.
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| - You won a battle with Hulk and Iron Man.
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| - You won a battle in CO-OP.
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- Ride the lightning (5 points)
| - You won a battle with Thor and Storm.
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| - You won a battle with Hawkeye and Black Widow.
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| - You won a battle with Super-Skrull and Veranke.
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- Speed and Power (15 points)
| - You reached the FAST velocity when doing a Super Attack 5 times in a row.
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| - You finished the Tutorial challenges.
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- Super Tag Combo (15 points)
| - You chained 3 Super Attacks by switching characters twice.
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| - You used your ULTRA Attack.
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| - You performed a 4x Combo in CO-OP.
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| - You chained two Super Attacks by switching characters.
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| - You fired projectiles during the ULTRA attack in CO-OP.
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| - You won a battle with Wolverine and Phoenix.
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| - You finished every Trial.
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- Uneasy Alliance (5 points)
| - You won a battle with Wolverine and Magneto.
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| - You won a fight without being hit in Campaign.
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