| Achievement | How to unlock
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| 50x Combo (5 points) | Complete a combo of 50 moves (any play mode, any character)
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| A Few New Tricks (20 points) | Use 5 different Quickfire gadgets in one fight as Robin in Harley Quinn's Revenge.
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| Acid Bath (10 points) | Save the damsel, but is she in distress?
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| Aggravated Assault (10 points) | Stop all assaults in Arkham City.
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| AR Knight (25 points) | Complete all augmented reality training exercises.
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| Arkham City Sirens (25 points) | Drop in on an old friend.
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| Bargaining Chip (15 points) | Reunite the separated couple.
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| Battering Ram (10 points) | Shield Bash 5 different thugs.
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| Bomb Squad (40 points) | Defuse all bombs in 3 minutes or less.
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| Brainteaser (40 points) | Rescue the fifth hostage from Riddler.
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| Breaking and Entering (20 points) | Find a way into the secret base.
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| Broken Toys (25 points) | Destroy it all.
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| Bronze Revenge (10 points) | Obtain 24 medals on the original Arkham City ranked maps (as Batman)
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| Campaign Bronze (10 points) | Obtain 36 medals on the original Arkham City campaigns (as Batman)
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| Campaign Gold (40 points) | Obtain all 108 medals on the original Arkham City campaigns (as Batman)
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| Campaign Kitty (25 points) | Obtain all 108 medals on the original Arkham City campaigns (as Catwoman)
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| Campaign Nightwing (25 points) | Obtain 114 medals on the original Arkham City and Nightwing Bundle Pack campaigns (as Nightwing)
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| Campaign Silver (20 points) | Obtain 72 medals on the original Arkham City campaigns (as Batman)
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| Campaign Wonder (25 points) | Obtain 114 medals on the original Arkham City and Robin Bundle Pack campaigns (as Robin)
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| Catch (5 points) | Find someone to play remote Batarang catch with.
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| Chimney Sweep (10 points) | There is only one way in.
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| Communication Breakdown (10 points) | Clear the airwaves.
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| Contract Terminated (25 points) | Stop the contract operative.
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| Conundrum (20 points) | Rescue the first hostage from Riddler.
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| Dial Z For Murder (25 points) | Stop the phone booth killer.
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| Distress Flare (5 points) | Answer the call for help.
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| Exit Stage Right (50 points) | All the world is a stage.
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| Family Jewels (40 points) | Retrieve your stolen goods.
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| Feline Revenge (25 points) | Obtain all 72 medals on the original Arkham City ranked maps (as Catwoman)
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| Flawless Freeflow Fighter 2.0 (5 points) | Complete one combat challenge without taking damage (any character)
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| Forensic Expert (10 points) | Collect enough evidence to locate the gun for hire.
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| Freefall (25 points) | Don't look down.
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| Frequent Flyer (10 points) | Zip Kick 5 different thugs.
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| Fully Loaded (10 points) | Collect all of Batman's gadgets and upgrades.
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| Gadget Attack (5 points) | Use 5 different Quickfire gadgets in one fight (any play mode)
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| Genius (50 points) | Rescue all the hostages from Riddler.
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| Ghost Train (25 points) | Fight for survival.
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| Gladiator (10 points) | Last man standing.
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| Gold Revenge (40 points) | Obtain all 72 medals on the original Arkham City ranked maps (as Batman)
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| Gotham Base Jumper (5 points) | Jump off the tallest building in Arkham City and glide for 1 minute without touching the ground.
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| Hide And Seek (25 points) | A deadly game of hide and seek.
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| How's It Hanging? (20 points) | Clean up the Dry Docks.
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| I'm Batman (10 points) | Become the Bat.
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| Intellectual (30 points) | Rescue the fourth hostage from Riddler.
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| IQ Test (10 points) | Solve the first riddle.
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| Lost And Found (10 points) | Uncover the secret of Arkham City.
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| Lost Property (20 points) | No crimefighter should be without this.
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| Mastermind (20 points) | Rescue the second hostage from Riddler.
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| Mystery Stalker (15 points) | Reveal the mystery watcher.
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| Nightwing Revenge (25 points) | Obtain 78 medals on the original Arkham City and Nightwing Bundle Pack ranked maps (as Nightwing)
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| One-Armed Bandit (10 points) | Hammer the point home.
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| Party's Over (50 points) | Destroy all Harley Balloons.
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| Pay Your Respects (5 points) | A moment of remembrance.
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| Perfect Freeflow 2.0 (5 points) | Perform a perfect combo including all of Batman's combat moves (any play mode)
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| Perfect Knight - Day 2 (75 points) | Main Story, Side Missions, Upgrades, Collectables, New Game Plus and Riddler's Revenge (as Batman)
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| Pick Pocket (25 points) | Steal the score of a lifetime.
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| Puzzler (30 points) | Rescue the third hostage from Riddler.
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| Ring Ring (5 points) | Answer a ringing phone.
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| Robin Revenge (25 points) | Obtain 78 medals on the original Arkham City and Robin Bundle Pack ranked maps (as Robin)
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| Sandstorm (25 points) | We are legion.
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| Savior (10 points) | Save the medical volunteers.
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| Serial Killer (25 points) | Track down the serial killer.
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| Silver Revenge (20 points) | Obtain 48 medals on the original Arkham City ranked maps (as Batman)
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| Snap To It (20 points) | Snap Flash an unarmed thug, an armed thug, an environmental object and a Titan.
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| Sphinx' Riddle (10 points) | Complete all 40 of the Catwoman Riddler grid items.
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| Stop the Clock (15 points) | Time is running out.
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| Storyteller (10 points) | Have 12 murderous dates with Calendar Man.
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| The Last Laugh (40 points) | The joke's on who?
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| Twice Nightly (75 points) | Complete New Game Plus.
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| Wrecking Ball (25 points) | Stop the unstoppable.
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