| Achievement | How to unlock
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| Adamantium (30 points) | You obtained an adamantium grade.
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| Army of One (50 points) | You won a fight without changing characters in Campaign.
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| Avengers (5 points) | You won a battle with Captain America and Iron Man.
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| Bad Intentions (5 points) | You won a battle with Super Skrull and Doctor Doom.
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| Breaker (5 points) | You used your Breaker to break a Combo.
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| Brothers (5 points) | You won a battle with Thor and Loki.
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| Champion (20 points) | You won a Tournament.
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| Closure (100 points) | You finished the Campaign mode.
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| Combo (5 points) | You chained two Super Attacks.
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| Completist (150 points) | You finished all character's challenge.
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| Counter (10 points) | You countered a Super Attack with another Super Attack.
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| Dodge this (5 points) | You dodged a Super Attack.
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| Earth United (30 points) | You finished the first part of the Campaign.
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| Escapist (5 points) | You performed a Counter Kick.
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| Experienced (20 points) | You got 100 000 Experience points.
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| Fashion (5 points) | You changed the costume of one of your character.
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| Fearless (50 points) | You won a match without dodging in Campaign.
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| Fire and Ice (5 points) | You won a battle with Human Torch and Iceman.
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| Heatwave (5 points) | You won a battle with Phoenix and Human Torch.
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| Here I am! (5 points) | You won your first battle in Campaign.
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| Impressive feet (5 points) | You performed a Close-Combat.
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| King of the Hill (20 points) | You won the arcade mode once.
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| Leading Ladies (5 points) | You won a battle with Scarlet Witch and Storm.
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| Legend (200 points) | You unlocked the highest Rank.
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| Maximum Combo (20 points) | You chained 4 Super Attacks by switching characters twice.
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| Need a Doctor? (5 points) | You won a battle with Doctor Doom and Doctor Strange.
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| Part of me (5 points) | You won a battle with Spider-Man and Venom.
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| Pioneers (5 points) | You won a battle with Hulk and Iron Man.
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| Power duo (5 points) | You won a battle in CO-OP.
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| Ride the lightning (5 points) | You won a battle with Thor and Storm.
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| S.H.I.E.L.D (5 points) | You won a battle with Hawkeye and Black Widow.
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| Skrulls (5 points) | You won a battle with Super-Skrull and Veranke.
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| Speed and Power (15 points) | You reached the FAST velocity when doing a Super Attack 5 times in a row.
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| Student (30 points) | You finished the Tutorial challenges.
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| Super Tag Combo (15 points) | You chained 3 Super Attacks by switching characters twice.
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| Super charged (5 points) | You used your ULTRA Attack.
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| Symbiosis (5 points) | You performed a 4x Combo in CO-OP.
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| Tag Combo (10 points) | You chained two Super Attacks by switching characters.
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| Team power (10 points) | You fired projectiles during the ULTRA attack in CO-OP.
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| The X-Men (5 points) | You won a battle with Wolverine and Phoenix.
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| Trialist (50 points) | You finished every Trial.
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| Uneasy Alliance (5 points) | You won a battle with Wolverine and Magneto.
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| Untouchable (50 points) | You won a fight without being hit in Campaign.
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