| Character | How to unlock
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| Cao Cao | Complete Wei Story Chapter 7.
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| Cao Ren | In SW Story Chapter 5-X, rescue the Takeda-Uesugi army within two minutes then escort the horsemen and defeat Cao Ren when he charges.
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| Da Ji | Complete all Chapters, including Chapter Chapters.
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| Da Qiao | In Wu Story Chapter 5-X. Meet Da Qiao by running up to her before the enemy does.
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| Date Masamune | Complete the optional missions in Shu Story Chapter 5.
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| Dian Wei | Complete Wei Story Chapter 7.
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| Diao Chan | Complete Wei Story Chapter 5 with Diao Chan surviving.
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| Dong Zhuo | In Sengoku Story Chapter 4, prevent all money supply troops from reaching Dong Zhuo.
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| Gan Ning | Complete Wei Story Chapter 6.
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| Ginchiyo Tachibana | Complete Shu Story Chapter 1.
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| Guan Ping | Complete SW Story Chapter 1.
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| Guan Yu | Complete Shu Story Chapter 7.
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| Huang Gai | Complete Wei Story Chapter 5.
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| Huang Zhong | Complete SW Story Chapter 1.
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| Inahime (Lady Ina) | Complete Wu Story Chapter 5.
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| Ishikawa Goemon | In Shu Story Chapter 4, break all of Goemon's treasure boxes.
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| Jiang Wei | In Shu Story Chapter 2-X initiate and have Jiang Wei's ambush plan succeed. Do this by luring the ambush generals into your main camp.
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| Kanetsugu Naoe | Complete SW Story Chapter 7.
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| Kotaro Fuuma | In Wu Story Chapter 2-X, defeat him after all supply troops have reached your headquarters.
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| Kunoichi | In Wu Story Chapter 4, successfully escort all peasants.
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| Ling Tong | Complete SW Story Chapter 5.
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| Liu Bei | Complete Shu Story Chapter 8.
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| Lu Bu | In all stories Chapter 8, impress Lu Bu by defeating him.
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| Lu Meng | Complete Wu Story Chapter 3.
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| Lu Xun | In SW Story Chapter 3-X escort Lu Xun to your HQ.
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| Ma Chao | In SW Story Chapter 2-X, have all peasants escape and Ma Chao survive.
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| Maeda Keiji | In Wu Story Chapter 6, make sure all ally reinforcements are alive and reach Keiji's base before the timer reaches 10 minutes remaining.
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| Meng Huo | Complete Shu Story Chapter 4.
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| Mitsunari Ishida | Complete Wei Story Chapter 2.
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| Mori Ranmaru | Complete Wu Story Chapter 1.
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| Musashi Miyamoto | In Shu Story Chapter 6-X. Successfully open the dam by escorting Miyamoto Musashi into it. Defeat Lu Bu and keep all the swordsmen alive.
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| Nagamasa Azai | Complete Wei Story Chapter 6.
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| Nene | In Wei Story Chapter 3-X. Defeat the two Nene clones within four minutes after their appearances.
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| Nouhime | In Wu Story Chapter 3, prevent all messengers from leaving the map.
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| Oichi | Complete Wei Story Chapter 6.
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| Okuni | Complete Sengoku Story Chapter 3.
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| Orochi | Unlock all other characters.
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| Pang De | In Shu Story Chapter 3-X, rescue all of the Hojo (yellow) generals.
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| Pang Tong | Complete Wei Story Chapter 4.
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| Saika Magoichi | Complete Shu Story Chapter 2.
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| Sakon Shima | Complete Wu Story Chapter 3.
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| Sanada Yukimura | Complete Shu Story Chapter 3.
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| Sima Yi | In SW Story Chapter 6-X, foil Sima Yi's strategy by killing the two retreating Orochi generals.
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| Sun Ce | Default character for Wu.
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| Sun Jian | Complete Wu Story Chapter 7.
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| Sun Quan | Complete Wu Story Chapter 7.
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| Sun Shang Xiang | Complete Wu Story Chapter 5.
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| Tadakatsu Honda | In ALL Stories Chapter 7-X, Impress Honda by defeating him as soon as possible.
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| Taishi Ci | Complete Wu Story Chapter 2.
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| Takeda Shingen | Complete Sengoku Story Chapter 7.
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| Uesugi Kenshin | Complete Sengoku Story Chapter 7.
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| Wei Yan | Complete Shu Story Chapter 3.
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| Xiahou Dun | Complete Wei Story Chapter 4.
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| Xiahou Yuan | Complete Wei Story Chapter 4.
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| Xiao Qiao | Complete SW Story Chapter 3.
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| Xing Cai | Default character for Shu.
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| Xu Zhu | Complete Wei Story Chapter 1.
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| Yoshihiro Shimazu | Default character for Shu.
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| Yoshimoto Imagawa | In Wei Story Chapter 4-X. Prevent all ploy troops from entering the village.
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| Yuan Shao | Complete Shu Story Chapter 5.
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| Yue Ying | Complete Shu Story Chapter 2.
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| Zhang Fei | Complete Shu Story Chapter 7.
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| Zhang He | In Wei Story Chapter 2-X. Rescue Zhang He by running up to him and initiating a conversation. Make sure he does not die in the battle.
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| Zhang Jiao | Complete Sengoku Story Chapter 3.
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| Zhang Liao | Default character for Wei.
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| Zhao Yun | Default character for Shu.
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| Zhen Ji | In Wei Story Chapter 6-X. Defeat all magicians that appear in the supply bases and the fake Cao Pi.
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| Zhou Tai | Complete Wu Story Chapter 6.
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| Zhou Yu | Complete Wu Story Chapter 1.
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| Zhu Rong | Complete Shu Story Chapter 4.
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| Zhuge Liang | Complete Shu Story Chapter 7.
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| Zuo Ci | Complete all four stories.
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