| Character | How to unlock
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|---|
| Bao Sanniang | Complete Stage 11X (Hypothetical) - Pacification of Nanzhong.
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| Guan Ping | Complete Stage 11X (Hypothetical) - Pacification of Nanzhong.
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| Guan Suo | Complete Stage 9 - Battle of Fan Castle.
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| Guan Xing | Complete Stage 9 - Battle of Fan Castle.
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| Guan Yinping | Complete Stage 9 - Battle of Fan Castle.
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| Huang Zhong | Complete Stage 7 - Battle of Chengdu.
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| Jiang Wei | Complete Stage 12 (Historical) - Battle of Jieting or Stage 12 (Hypothetical) - Invasion of Luoyang.
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| Liu Shan | Complete Stage 11 (Historical) - Battle of Tianshui or Stage 13 (Hypothetical) - Capture of Wei.
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| Ma Chao | Complete Stage 8 - Battle of Mt. Dingjun.
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| Ma Dai | Complete Stage 8 - Battle of Mt. Dingjun.
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| Pang Tong | Complete Stage 7 - Battle of Chengdu.
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| Wei Yan | Complete Stage 7 - Battle of Chengdu.
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| Xing Cai | Complete Stage 11 (Historical) - Battle of Tianshui or Stage 10 (Hypothetical) - Battle of Lukou.
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| Xu Shu | Complete Stage 4 - Battle of Xinye.
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| Yue Ying | Complete Stage 12 (Historical) - Battle of Jieting.
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| Zhang Bao | Complete Stage 10 (Historical) - Battle of Yiling or Stage 10 (Hypothetical) - Battle of Lukou.
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| Zhao Yun | Complete Stage 2 - Battle of Hulao Gate.
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| Zhuge Liang | Complete Stage 5 - Battle of Changban.
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| Character | How to unlock
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|---|
| Cai Wenji | Complete Stage 11(IF) - Invasion of Jianye.
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| Cao Cao | Starting Character.
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| Cao Pi | Complete Stage 6 - Battle of Wan Castle.
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| Cao Ren | Complete Stage 4 - Battle of Xu Province.
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| Dian Wei | Complete Stage 6 - Battle of Wan Castle.
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| Guo Jia | Complete Stage 6 - Battle of Wan Castle.
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| Jia Xu | Complete Stage 6 - Battle of Wan Castle.
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| Li Dian | Complete Stage 1 - Dong Zhuo’s Assassination.
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| Pang De | Complete Stage 13(IF) - Chase at Nanjun.
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| Wang Yi | Complete Stage 11 - Battle of Tong Gate.
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| Xiahou Dun | Starting Character.
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| Xiahou Yuan | Starting Character.
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| Xu Huang | Complete Stage 4 - Battle of Xu Province.
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| Xu Zhu | Complete Stage 3 - Battle of Yan Province.
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| Yue Jin | Complete Stage 1 - Dong Zhuo’s Assassination.
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| Zhang He | Complete Stage 12 - Battle of He Fei.
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| Zhang Liao | Complete Stage 6A - Battle of Xia Pi.
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| Zhenji | Complete Stage 12(IF) - Defense of Xu Chang.
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| Character | How to unlock
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|---|
| Daqiao | Complete Stage 3(x) - Battle against Yu Ji.
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| Ding Feng | Complete Stage 10 - Battle of Yiling.
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| Gan Ning | Complete Stage 6 - Battle of Jingzhou.
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| Han Dang | Starting Character.
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| Huang Gai | Complete Stage 1 - Assault of Liu Biao.
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| Lianshi | Complete Stage 8 - Battle of Ru Xu Kou.
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| Ling Tong | Complete Stage 6 - Battle of Jingzhou.
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| Lu Meng | Complete Stage 7 - Battle of He Fei.
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| Lu Su | Complete Stage 3 - Battle of Xu Chang.
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| Lu Xun | Complete Stage 8 - Battle of Ru Xu Kou.
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| Sun Ce | Starting Character.
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| Sun Jian | Complete Stage 1(x) - Battle of Liang Province.
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| Sun Quan | Starting Character.
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| Sun Shangxiang | Starting Character.
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| Taishi Ci | Complete Stage 7 - Battle of He Fei.
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| Xiaoqiao | Complete Stage 9(IF)(x) - Battle of Xinye.
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| Zhou Tai | Complete Stage 2 - Conquest of Wu.
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| Zhou Yu | Complete Stage 1 - Assault of Liu Biao.
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| Trophy | How to unlock
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|---|
| A Collector of Rarities (Silver) | Obtained all of the Camp Symbols.
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| A Majestic Manner (Silver) | Reached the maximum Fame level in Ambition Mode.
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| A Shout of Triumph (Silver) | Finished all of the stages within Story Mode and Free Mode with the exception of the tutorial.
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| An Intricate Tale (Silver) | Completed all of the stages in Story Mode.
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| Animal Collector (Bronze) | Obtained all of the animals within the game.
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| Battle-hardened Veteran (Silver) | Won 100 battles with the same officer.
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| Comeback Kid (Bronze) | Defeated 3 enemy officers with a Switch Counter in a single battle.
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| Death from Above (Bronze) | Defeated an enemy after juggling them in the air for at least 10 seconds.
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| Event Collector (Bronze) | Unlocked all of the event scenes within the game.
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| Facility Construction (Bronze) | Had a new facility built in Ambition Mode.
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| Facility Expansion (Bronze) | Had a facility expanded in Ambition Mode.
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| Friends to the End (Silver) | Formed a bond at the maximum level with another officer.
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| Graduation Day (Bronze) | Completed the tutorials for all of the kingdoms.
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| Heaven and Earth (Silver) | Built a Tongquetai and welcomed the Emperor to your town.
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| In an Instant (Bronze) | Defeated 3 enemy officers with a Storm Rush in a single battle.
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| King of the Combos (Bronze) | Achieved a 1,000 hit combo.
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| Like a Shadow (Bronze) | Finished any stage of the game, except for the tutorial, without taking any damage.
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| Master of Chaos (Gold) | Completed all of the stages on the "Chaos" difficulty level.
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| Mounted Terror (Bronze) | Defeated 1,000 enemies while mounted on a riding-type animal.
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| Movie Collector (Bronze) | Unlocked all of the movies within the game.
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| One Warrior vs. a Thousand (Bronze) | Defeated 1,000 enemies in a single battle.
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| Revelation (Silver) | Upgraded all skills to Level 10 or higher.
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| The Beastmaster Awakens (Bronze) | Defeated 100 enemies with a companion-type animal.
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| The Birth of a Leader (Bronze) | Fought 5 straight battles in Ambition Mode.
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| The Destroyer (Silver) | Destroyed a total of 1,000 siege weapons.
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| The Height of Prosperity (Silver) | Obtained all of the facilities in Ambition Mode.
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| The Land of Plenty (Silver) | Obtained more than 1,000 materials for weapons and facilities in Ambition Mode.
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| The Path of Ambition (Silver) | Fought 20 straight battles in Ambition Mode.
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| The Ties that Bind Us (Silver) | Became allies with all of the officers in Ambition Mode.
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| True Rage (Bronze) | Used a True Rage Attack.
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| True Warrior of the 3 Kingdoms (Platinum) | Obtained all trophies.
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| Unwavering Ambition (Gold) | Fought 50 straight battles in Ambition Mode.
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| Vocal Enthusiast (Bronze) | Listened to all of the voice lines within the Gallery.
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| Wallpaper Collector (Bronze) | Unlocked all of the wallpapers within the game.
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| Weapon Collector (Silver) | Obtained all of the weapons in the game.
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