Don't Starve: Giant Edition (PlayStation 3)
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Maxwell
Finish Adventure mode.
Webber
His skull will sometimes drop from defeated spiders. Bury it in a grave mound to unlock him.
Wendy
Survive for 32 days.
Wes
Rescue Wes in Adventure.
Wickerbottom
Survive for 64 days.
Wigfrid
Gain 1920 experience by surviving for 96 days.
Willow
Survive for 8 days.
Wolfgang
Survive for 16 days.
Woodie
Survive for 80 days.
WX-78
Survive for 48 days.