Successfully complete all Episodes with an "A" or "S" rank, have at lease 660 points in Destruction mode, have 100 mission points, and successfully complete Battle mode two times as Ultraman.
Play as Bullton
Successfully complete Episode 1 and have 10 mission points.
Play as Chaos Kyrieloid
Successfully complete Episode 5 and have 30 mission points.
Play as Chaos Waroga
Successfully complete Episode 11.
Play as Chaosroid S
Successfully complete Episode 12.
Play as Chaosroid T
Successfully complete Episode 12 and have 60 mission points.
Play as Chaosroid U
Successfully complete Episode 12 and have 90 mission points.
Play as EX Eleking
Successfully complete Episode 3.
Play as EX Gomora
Successfully complete Episode 6.
Play as EX Redking
Successfully complete Episode 5.
Play as EX Tyrant
Successfully complete Episode 8 and have 40 mission points.
Play as EX Tyrant II
Successfully complete Episode 18 and have 70 mission points.
Play as Geronimon
Successfully complete Episode 9 and have 50 mission points.
Play as Neo Chaos Darkness
Successfully complete Episode 13 and have 80 mission points.
Play as Redking
Successfully complete Episode 2.
Play as Ultraman Agul V2
Successfully complete Episode 7 and have 20 mission points.