Spider-Man: Web of Shadows (PlayStation 2)

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Unlock Big Wheel

Keep choosing the bad choice when you asked by computer (after beating Tinkerer).

Unlock Black Cat

Choose to save Black cat when you fight her (pick the 1st choice when asked by Smythe).

Unlock Hobgoblin

Keep choosing the bad choice (the 2nd/3rd choice) before fighting Kraven.

Unlock Jessica Drew

Choose to help Shield crew from the symbiote (before you fight with Jessica Drew).

Unlock Luke Cage

Make the bad choice (2nd choice) when you asked by a man who say he can divert the train containing symbiote.

Unlock Random Assist

You can get mysterio, Night Crawler, Wolverine, Ctylok, Galactus, Hypno Hustler randomly by beating any level or buying the ultra rare powe ups.

Unlock Shocker

Choose to free Shocker after defeating him.

Unlock Solidarity

Bring shocker to jail (after beating him).

Unlock Storm

Keep choosing the good answer when you asked by computer after defeating Tinkerer.