Spider-Man: Web of Shadows (PlayStation 2)
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Unlock Big Wheel
Keep choosing the bad choice when you asked by computer (after beating Tinkerer).
Unlock Black Cat
Choose to save Black cat when you fight her (pick the 1st choice when asked by Smythe).
Unlock Hobgoblin
Keep choosing the bad choice (the 2nd/3rd choice) before fighting Kraven.
Unlock Jessica Drew
Choose to help Shield crew from the symbiote (before you fight with Jessica Drew).
Unlock Luke Cage
Make the bad choice (2nd choice) when you asked by a man who say he can divert the train containing symbiote.
Unlock Random Assist
You can get mysterio, Night Crawler, Wolverine, Ctylok, Galactus, Hypno Hustler randomly by beating any level or buying the ultra rare powe ups.
Unlock Shocker
Choose to free Shocker after defeating him.
Unlock Solidarity
Bring shocker to jail (after beating him).
Unlock Storm
Keep choosing the good answer when you asked by computer after defeating Tinkerer.