Find Archive 087 in Kyoya Sudo's stage (03:00 on Day 3).
Break strangleholds
If you get too close to a regular Shibito, it will sometimes prefer to grab you by the neck and choke you to death instead of doing a regular attack. When one takes you into a stranglehold, rapidly move the Left Analog-stick Up and Down.
This will break the hold, and prevent you from dying.
Hidden FMV sequence
Successfully complete the game after finding all 100 Archives. A bonus FMV sequence will be unlocked at the top right corner of the scenario selection screen.
Mission Objectives 2
To unlock Mission Objectives 2 for every character and/or scenario, complete 19 stages in any order. Then, press L1 + R1 while the stage is highlighted at the scenario selection screen. Note: You will automatically obtain it after completing the random 19 stages.
Time attack mode
Successfully complete the first two objectives on all levels in every scenario to unlock the first ending sequence. Then, press Square at the scenario selection screen.