| Unlockable | How to Unlock
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|---|
| Cao Cao | Clear 3 Wei Musou Modes
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| Cao Ren | Complete target 2 Fan Castle - Lu Bu side
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| Chaos Difficulty | Complete 1 Wei, Shu, Wu, Other Musou Mode
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| Character Costumes | Raise a character to level 50
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| Diao Chan | Complete 1 Wei, Shu, Wu Musou Mode
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| Dong Zhuo | Complete target 1 Hu Lao Gate - Lu Bu side
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| Gan Ning | Complete 1 Wu Musou Mode
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| Guan Ping | Complete target 2 Fan Castle - Shu side
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| Huang Gai | Complete target 3 Chi Bi - Wu side
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| Huang Zhong | Complete target 1 Ding Jun - Wei side
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| Liu Bei | Complete 3 Shu Musou Mode
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| Lu Bu | Complete Sun Jian, Liu Bei, Cao Cao, and Diao Chan usou mode
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| Sun Jian | Complete 3 Wu Musou Mode
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| Sun Quan | Succeed in Battle Objective 1 on the Lu Bu side of The Battle of Chi Bi
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| Very Hard Difficulty | Clear Musou Mode with any character
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| Voice Gallery | Raise a character to level 50
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| Wei Yan | Succeed in 2 battle objectives on the Shu side of WuZhang Plains and finish battle with Wei Yan alive
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| Zhang Liao | Complete 1 Wei Musou Mode
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| Zhuge Liang | Complete 1 Shu Musou Mode
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