| Character | How to unlock
|
|---|
| Andy | Complete the Job:"Throwdown Challenge: Dragons"
|
| Boris | Complete the Job "Showdown: Dodgeball"
|
| Crush | Complete the Job "Throwdown Challenge: Thornley"
|
| Demon Lion | Defeat him in Ueno during Story Mode
|
| Gold Lion | In New Game +, Defeat Gold Lion in Akihabara during Story Mode
|
| Hiroshi | Simply watch the beginning cutscene upon starting a New Game
|
| Ivan | Compete the Job "Throwdown Challenge: Partners"
|
| Lee | Beat the game and save after the credits roll
|
| Maezawa | Complete the Job "Stand-In Gladiator 2"
|
| Misuzu | Defeat and Recruit her in Shinjuku during Story Mode
|
| Nizaemon | Complete the Job "Nizaemon Bounty"
|
| Okada | Complete the Job "Stand-In Gladiator"
|
| Randy | Complete the Job :"Throwdown Challenge: Dragons"
|
| Rip | Complete the Job "Jock Bounty"
|
| Rocko | Complete the Job "Throwdown Challenge: Thornley"
|
| Rouge Lion | Defeat her in Shibuya during Story Mode
|
| Sabu | Beat the game and save after the credits roll
|
| Sakata | Defeat Sakata in the intro chapter of Story Mode
|
| Sakyo | Defeat him in Asakusa during Story Mode
|
| Saotome | Complete the Job "Throwdown Challenge: Rivals"
|
| Shinji | Defeat and Recruit him in Yokohama during Story Mode
|
| Silver Lion | Defeat him in Akihabara during Story Mode
|
| Skates | Complete the Job "Get My Mask Back!"
|
| Swole | Complete the Job "Jock Bounty"
|
| Tex | Complete the Job "Throwdown Challenge: Partners"
|
| Tigerclaw | Complete the Job "Throwdown Challenge: Tigers"
|
| Tigerfang | Complete the Job "Throwdown Challenge: Tigers"
|
| Ukyo | Defeat him in Asakusa during Story Mode
|
| Ultra Lion | Defeat him in Shinagawa during Story Mode
|
| Yemi | Complete the Job "Showdown: Dodgeball"
|