| Character | How to unlock
|
|---|
| Akainu | Defeated 90 strong enemies, performed 6 link attacks, and defeated Akainu with Ace 1 time.
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| Black Leg Sanji | Be promoted to B league.
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| Brook | Win 2 fights with Sanji and any female character.
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| Buggy | Clear 1 Boss Rush and Clear 3 Battle Royales with Luffy.
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| Chopper | Place 1st in C league.
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| Crocodile | Pull off 15 dodges with Hancock and trigger 5 item word effects.
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| Fire-fist Ace | Clear 5 Battle Royales and perform 1 link attack.
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| Franky | Pull off 6 counters with Zoro.
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| Fujitora | Cleared 3 scrambles with Doflamingo, defeated 25 bosses with Akainu, and performed 12 special attacks with Akainu.
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| Hancock | Clear 3 scrambles.
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| Jimbei | Perform 8 special attacks with Ace, Pull off 110 dodges with Ace, and perform 2 link attacks with Luffy and Ace.
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| Monkey D. Luffy | Beginning.
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| Nami | Clear 2 duels.
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| Robin | Clear 2 battles with Nami.
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| Roronoa Zoro | Be promoted to B league.
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| Shanks | Defeated 20 bosses with Buggy, performed 2 link attacks with Buggy, and pulled off 25 dodges with Buggy.
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| Trafalgar Law | Beginning.
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| Usopp | Place 1st in C league.
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| Whitebeard | Defeat 600 enemies with Shanks, Win 3 battles with Ace and Jimbei, and beat the battle coliseum.
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