| Achievement | How to unlock
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| 00 Agent (30 points) | Public Match: Reach level 50 (00 Agent Grade 0).
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| 007 (50 points) | Complete all levels on a 'Classic' difficulty.
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| A Farewell to Arms (50 points) | Multiplayer: Enter 00 Specialization.
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| Above and Beyond a 00 (30 points) | Complete three of the '007' level trials.
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| All That Glitters (10 points) | Earn a 3 star rating in any mission of the Challenges mode.
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| All the Time in the World (40 points) | Public Match: Play for more than 24 hours.
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| Around the world one more time (20 points) | Get 100% collection rating for 'Moonraker'.
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| Boys with Toys (10 points) | Campaign: Buy all of the attachments for one weapon class.
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| Challenger (20 points) | Earn a 1 star rating in each mission of the Challenges mode.
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| Clandestine (10 points) | Campaign: Collect 100% of all organization intel.
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| Counter-Sniper (25 points) | Public Match: Kill 50 players while they are aiming down the scope of a sniper rifle.
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| Danger! High Voltage (10 points) | Public Match: Get 25 electrocution kills as Zao or Gustav Graves.
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| Die Another Day (15 points) | Complete the 'Die Another Day' mission.
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| Disarmed and Dangerous (20 points) | Public Match: In Escalation demote an enemy who is armed with the RPG.
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| Distracting (10 points) | Distract an enemy.
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| Everything or Nothing (5 points) | Complete all of the trials on any one level.
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| Extended Operative (20 points) | Complete eight of the 'Operative' level trials.
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| Fascination with all things gold (60 points) | Get 100% of all available stars in the Challenges mode.
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| Goldfinger (15 points) | Complete the 'Goldfinger' mission.
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| Happy Snapper (10 points) | Campaign: Take a photograph of the crocodile.
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| Hold the Line (30 points) | Public Match: Win a Data Miner match without being killed.
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| I expect you to die (20 points) | Get 100% collection rating for 'Goldfinger'.
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| Laser Eraser (15 points) | Public Match: Win a match using only laser-based weapons.
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| Licence To Kill (15 points) | Complete the 'License To Kill' mission.
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| Making it Personal (10 points) | Campaign: Collect 100% of all character bio intel.
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| Master at Arms (20 points) | Make an elimination with every weapon class.
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| Midas Touch (15 points) | Public Match: Win a match on Main Vault, Smelting Room and Loading Bay.
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| Moonraker (15 points) | Complete the 'Moonraker' mission.
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| More Than an Agent (25 points) | Complete six of the 'Agent' level trials.
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| Never happened to the other guy (20 points) | Get 100% collection rating for 'O.H.M.S.S.'
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| O.H.M.S.S. (15 points) | Complete the 'O.H.M.S.S.' mission.
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| People Power (10 points) | Campaign: Collect 30% of all character bio intel.
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| Positively shocking! (12 points) | Take out two enemies with one shock dart.
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| Return to Sender (35 points) | Public Match: In Bomb Defuse disarm the bomb and plant it at enemy base without getting killed.
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| Scream if you want to go faster (10 points) | Campaign: Give someone an exciting training experience.
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| Secret Agent (50 points) | Complete all levels on "Agent" difficulty or higher.
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| Shaken, but not Stirred (10 points) | Public Match: Survive 50 explosions while using Reactive Armor.
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| Shooting Star (20 points) | Get 30% of all available stars in the Challenges mode.
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| Spend the money quickly Mr. Bond (20 points) | Campaign: Be awarded a total of 10,000 XP.
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| Standards of Physical Perfection (30 points) | Campaign: Acquire all of the MI6 training modules.
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| Star Struck (40 points) | Get 60% of all available stars in the Challenges mode.
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| Unlocked and Loaded (5 points) | Public Match: Reach level 6 (Midshipman).
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| Very novel Q (10 points) | Campaign: Upgrade a gadget to its highest level.
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| Vodka martini, plenty of ice... (20 points) | Get 100% collection rating for 'Die Another Day'.
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| Web of Intrigue (10 points) | Campaign: Collect 30% of all organization intel.
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| You prepare for the unexpected (20 points) | Get 100% collection rating for 'License To Kill'.
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