| Character | How to unlock
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|---|
| Baraggan Luisenbarn/No.2nd Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Byakuya Kuchiki/Bankai | Unlock in Story Mode.
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| Coyote Starrk/No.1st Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Grimmjow Jaegerjaquez/No. 6 Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Ichigo Kurosaki/Bankai | Unlocked from the start.
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| Ichigo Kurosaki/Final Tensa Zangetsu Bankai Form ) | Unlock in Story Mode.
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| Ichigo Kurosaki/Hollowfied ) | Unlock in Story Mode.
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| Ichimaru Gin | Unlock in Story Mode.
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| Kenpachi Zaraki/Shikai ) | Unlock in Story Mode.
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| Kokuto the Bleach Movie 4 villain | Mission Mode.
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| Nnoitra Gilga/No.5th Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Rukia Kuchiki/Shikai | Unlock in Story Mode.
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| Shunsui Kyoraku/Shikai | Unlock in Story Mode.
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| Soi Fon/Shikai | Unlock in Story Mode.
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| Sosuke Aizen/Long Hair Chrysalis Form | Unlock in Story Mode.
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| Tia Harribel/No.3rd Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Toshiro Hitsugaya/Banka | Unlock in Story Mode.
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| Ulquiorra Cifer/No.4th Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Uryu Ishida/Hueco Mundo Arc Appearance | Unlock in Story Mode.
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| Yoruichi Shihoin/Anti-Hierror Armor | Unlock in Story Mode.
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| Trophy | How to unlock
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|---|
| All of Heaven is Under My Command! (Bronze) | Stay airborne for 30 seconds.
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| Amazing! (Bronze) | Complete 1 battle with all collections unlocked.
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| Amor! (Bronze) | Complete 1 battle after playing over 50 hours.
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| Aren't We Your Friends? (Bronze) | Complete 1 battle with all characters unlocked.
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| Come at Me! (Silver) | Defeat over 350 enemies in Beat Attack.
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| Come On! (Bronze) | Defeat 10,000 Soul Reapers.
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| Cough! Cough! (Bronze) | Complete 1 battle while near death.
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| Devour, Glotoneria! (Bronze) | Defeat 33,650 Hollows.
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| Did You Read This Week's Jump? (Bronze) | Jump 100 times in 1 battle.
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| Don't Be Scared (Bronze) | Beat all episodes on HARD.
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| Don't Beg for Your Life (Bronze) | Complete 1 battle in Soul Attack Mode.
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| Hmph, Too Slow (Silver) | Finish Time Attack in less than 1 minute 30 seconds.
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| Hueco Mundo is a Treasure Trove! (Bronze) | Defeat 10,000 Arrancars.
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| I am the King! (Silver) | Complete all battles in Soul Attack Mode.
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| I Can Fire 1200 (Bronze) | Perform a 1,000 Slash combo.
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| I Was Waiting For This! (Silver) | Max out 10 characters' levels.
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| I Will Transcend All (Platinum) | Obtain all trophies.
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| I Wish You Luck (Bronze) | Complete 1 mission.
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| I'll Be Okay Now (Bronze) | Complete 10 missions.
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| I'll Kick Your Butt! (Bronze) | Complete 1 battle with a final body count of 69.
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| I'll Take Care of It! (Bronze) | Save 30,000 Soul Points for 1 character.
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| I'll Try! (Bronze) | Beat 1 Story episode.
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| I'm Espada's Strongest! (Bronze) | Max out 1 character's levels.
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| I've Completely Analyzed You (Bronze) | Defeat every kind of enemy.
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| Is That It? (Gold) | Complete all missions with all characters.
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| More! More! (Bronze) | Obtain 1,000 items.
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| Mornin' Ichigo! (Bronze) | Defeat a boss using a dash charge.
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| No Need to Thank Me (Bronze) | Watch the credits once without skipping.
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| Not Bad! (Silver) | Complete all missions on VERY HARD.
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| Now Do You Understand? (Gold) | Max out all characters' levels.
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| Que Suerte! (Bronze) | Complete 1 battle with identical Soul Point digits.
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| Raaaaagh! (Bronze) | Power up 300 times.
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| Render All Things in the Universe to Ashes! (Silver) | Complete all missions with Rank S.
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| Snap Out of It, Baldy! (Bronze) | Air Recover 30 times in 1 battle.
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| Stand Behind Me! (Bronze) | Destroy 10,000 environmental objects.
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| The Shark Will Destroy You (Bronze) | Use your Ignition Attack 5 times in 1 battle.
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| Then What is Justice?! (Bronze) | Complete 1 battle without destroying any objects.
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| This is Art! (Bronze) | Perform a 2,000 Slash combo.
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| This is It for You! (Bronze) | Beat all episodes on VERY HARD.
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| Victory! (Bronze) | Defeat a boss using an Ignition Attack.
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| Want an Allowance? (Bronze) | Obtain a total of 1,000,000 Soul Points.
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| What a Pain in the Ass (Bronze) | Defeat 300 enemies in 1 battle.
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| What a Wonderful Power (Bronze) | Beat all episodes.
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| What...?! (Bronze) | See the Game Over screen 20 times.
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| Woohoo! (Bronze) | Complete all missions.
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| You are Simply Outclassed (Silver) | Beat all episodes with Rank S.
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| You Can't Read My Movements (Bronze) | Perform 100 Counters.
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| You Got Weird Tastes (Bronze) | Watch the opening movie 3 times without skipping.
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| You Think You Can Catch Me? (Bronze) | Complete 1 battle without taking damage.
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| You're Pretty Good (Silver) | Obtain over 8,000 Soul Points in Soul Attack.
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| Your Spiritual Power is Mine (Bronze) | Complete 1 battle without using Spirit Pressure attacks.
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