| Character | How to unlock
|
|---|
| Anna | Successfully complete Shaman King mode with Jeanne.
|
| Hao | Successfully complete Shaman King mode with Anna.
|
| Jeanne | Successfully complete Shaman King mode with Manta.
|
| Lyserg | Successfully complete Shaman King mode with Yoh.
|
| Manta | Successfully complete Manta's Story mode.
|
| Marco | Successfully complete Story mode.
|
| Redseb | Successfully complete Shaman King mode with Chocolove.
|
| Satei | Successfully complete Shaman King mode with Lyserg.
|
| Senjuu | Successfully complete Shaman King mode with Hao.
|