| Achievement | How to unlock
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| 00 Agent | Public Match: Reach level 50 (00 Agent Grade 0).
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| 007 | Complete all levels on a 'Classic' difficulty.
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| A Farewell to Arms | Multiplayer: Enter 00 Specialization.
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| Above and Beyond a 00 | Complete three of the '007' level trials.
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| All That Glitters | Earn a 3 star rating in any mission of the Challenges mode.
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| All the Time in the World | Public Match: Play for more than 24 hours.
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| Around the world one more time | Get 100% collection rating for 'Moonraker'.
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| Boys with Toys | Campaign: Buy all of the attachments for one weapon class.
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| Challenger | Earn a 1 star rating in each mission of the Challenges mode.
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| Clandestine | Campaign: Collect 100% of all organization intel.
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| Counter-Sniper | Public Match: Kill 50 players while they are aiming down the scope of a sniper rifle.
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| Danger! High Voltage | Public Match: Get 25 electrocution kills as Zao or Gustav Graves.
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| Die Another Day | Complete the 'Die Another Day' mission.
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| Disarmed and Dangerous | Public Match: In Escalation demote an enemy who is armed with the RPG.
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| Distracting | Distract an enemy.
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| Everything or Nothing | Complete all of the trials on any one level.
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| Extended Operative | Complete eight of the 'Operative' level trials.
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| Fascination with all things gold | Get 100% of all available stars in the Challenges mode.
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| Goldfinger | Complete the 'Goldfinger' mission.
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| Happy Snapper | Campaign: Take a photograph of the crocodile.
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| Hold the Line | Public Match: Win a Data Miner match without being killed.
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| I expect you to die | Get 100% collection rating for 'Goldfinger'.
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| Laser Eraser | Public Match: Win a match using only laser-based weapons.
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| Licence To Kill | Complete the 'Licence To Kill' mission.
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| Making it Personal | Campaign: Collect 100% of all character bio intel.
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| Master at Arms | Make an elimination with every weapon class.
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| Midas Touch | Public Match: Win a match on Main Vault, Smelting Room and Loading Bay.
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| Moonraker | Complete the 'Moonraker' mission.
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| More Than an Agent | Complete six of the 'Agent' level trials.
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| Never happened to the other guy | Get 100% collection rating for 'O.H.M.S.S.'
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| O.H.M.S.S. | Complete the 'O.H.M.S.S.' mission.
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| Omega Virus | Public Match: Kill an enemy who has completed the campaign or who already has this Achievement.
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| One small step for a man | Experience zero-g.
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| People Power | Campaign: Collect 30% of all character bio intel.
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| Positively shocking! | Take out two enemies with one shock dart.
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| Return to Sender | Public Match: In Bomb Defuse disarm the bomb and plant it at enemy base without getting killed.
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| Scream if you want to go faster | Campaign: Overload the gyroscopic training machine in the Space Port.
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| Secret Agent | Complete all levels on 'Agent' difficulty or higher.
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| Shaken, but not Stirred | Public Match: Survive 50 explosions while using Reactive Armor.
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| Shooting Star | Get 30% of all available stars in the Challenges mode.
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| Signature | Campaign: Reach level three weapon proficiency with the P99.
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| Spend the money quickly Mr. Bond | Campaign: Be awarded a total of 10,000 XP.
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| Standards of Physical Perfection | Campaign: Acquire all of the MI6 training modules.
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| Star Struck | Get 60% of all available stars in the Challenges mode.
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| Unlocked and Loaded | Public Match: Reach level 6 (Midshipman).
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| Very novel Q | Campaign: Upgrade a gadget to its highest level.
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| Vodka martini, plenty of ice... | Get 100% collection rating for 'Die Another Day'.
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| Web of Intrigue | Campaign: Collect 30% of all organization intel.
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| With or Without Q | Reach Grave’s plane without using any in-car gadgets.
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| You prepare for the unexpected | Get 100% collection rating for 'Licence To Kill'.
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